| No. | Portrait | Minister (Constituency)
 | Term of office | Political party | Ministry | Chief Minister | 
  | From | To | Period | 
  | Minister of Higher and Technical Education | 
  | 01 |  |  | Balasaheb Desai (MLA for Patan Constituency No. 261-
 Satara District)
 (Legislative Assembly)
 | 01 May 1960
 | 07 March 1962
 | 1 year, 310 days | Indian National Congress | Yashwantrao I |   Yashwantrao Chavan
 | 
  | 02 |  |  | Madhukar Dhanaji Chaudhari (MLA for Raver Constituency No. 11-
 Jalgaon District)
 (Legislative Assembly)
 | 08 March 1962
 | 19 November 1962
 | 256 days | Indian National Congress | Yashwantrao II | 
  | 03 |  |  | Balasaheb Desai (MLA for Patan Constituency No. 261-
 Satara District)
 (Legislative Assembly)
 | 20 November 1962
 | 24 November 1963
 | 1 year, 4 days | Indian National Congress | Kannamwar l | Marotrao Kannamwar | 
  | 04 |  |  | Parashuram Krishnaji Sawant (MLA for Chiplun Constituency No. 265-
 Ratnagiri District)
 (Legislative Assembly)
 (Interim Chief Minister)
 | 25 November 1962
 | 04 December 1963
 | 9 days | Indian National Congress | Sawant | Parashuram Krishnaji Sawant | 
  | 05 |  |  | Madhukar Dhanaji Chaudhari (MLA for Raver Constituency No. 11-
 Jalgaon District)
 (Legislative Assembly)
 | 05 December 1963
 | 01 March 1967
 | 3 years, 86 days | Indian National Congress | Vasantrao I |  Vasantrao Naik
 | 
  | 06 |  |  | D. S. Palaspagar (MLC for Elected by MLAs Constituency No. 19 -
 Bhandara District)
 (Legislative Council)
 | 01 March 1967
 | 27 October 1969
 | 2 years, 240 days | Indian National Congress | Vasantrao II | 
  | 07 |  |  | Sheshrao Krishnarao Wankhede (MLA for Sawargoan Constituency No. 49-
 Nagpur District)
 (Legislative Assembly)
 | 27 October 1969
 | 13 March 1972
 | 2 years, 138 days | Indian National Congress | 
  | 08 |  |   | Pratibha Patil (MLA for Jalgaon City Constituency No. 13-
 Jalgaon District)
 (Legislative Assembly)
 | 13 March 1972
 | 04 April 1973
 | 1 year, 32 days | Indian National Congress | Vasantrao III | 
  | 09 |  | .jpg)  | Abdul Rahman Antulay (MLA for Shrivardhan Constituency No. 193-
 Raigad District)
 (Legislative Assembly)
 | 04 April 1973
 | 17 Match 1974
 | 347 days | Indian National Congress | 
  | 10 |  | .jpg)  | Vasantrao Patil (MLC for Elected by MLAs Constituency No. 20 -
 Sangli District)
 (Legislative Council)
 | 17 Match 1974
 | 21 February 1975
 | 341 days | Indian National Congress | 
  | 11 |  |   | Pratibha Patil (MLA for Jalgaon City Constituency No. 13-
 Jalgaon District)
 (Legislative Assembly)
 | 21 February 1975
 | 16 April 1977
 | 2 years, 54 days | Indian National Congress | Shankarrao I |  Shankarrao Chavan
 | 
  | 12 |  |  | Vasant Hoshing (MLA for Byculla Constituency No. 184-
 Mumbai City District
 (Legislative Assembly)
 | 17 April 1977
 | 07 March 1978
 | 1 year, 324 days | Indian National Congress | Vasantdada I | .jpg) Vasantdada Patil
 | 
  | 13 |  |  | Purushottam Dekate (MLA for Umred Constituency No. 51-
 Nagpur District
 (Legislative Assembly)
 | 07 March 1978
 | 18 July 1978
 | 133 days | Indian National Congress (Indira) | Vasantdada II | 
  | 14 |  |  | Nihal Ahmed Maulavi Mohammed Usman (MLA for Malegaon Central Constituency No. 114-
 Nashik District)
 (Legislative Assembly)
 | 18 July 1978
 | 18 February 1980
 | 1 year, 215 days | Janata Party | Pawar I | .jpg) Sharad Pawar
 | 
  | 15 |  |  | Shivajirao Patil Nilangekar (MLA for Nilanga Constituency No. 238-
 Latur District)
 (Legislative Assembly)
 | 09 June 1980
 | 21 January 1982
 | 1 year, 226 days | Indian National Congress | Antulay | .jpg)  Abdul Rahman Antulay
 | 
  | 16 |  |  | Sharadchandrika Suresh Patil (Minister of Technical Education)
 (MLA for Chopda Constituency No. 10-
 Jalgaon District)
 (Legislative Assembly)
 | 21 January 1982
 | 02 February 1983
 | 1 year, 12 days | Indian National Congress | Bhosale |   Babasaheb Bhosale
 | 
  | 17 |  |  | Baburao Kale (Minister of Higher Education)
 (MLA for Ghansavangi Jalna Constituency No. 190-
 Jalna District)
 (Legislative Assembly)
 | 21 January 1982
 | 02 February 1983
 | 1 year, 12 days | Indian National Congress | 
  | 18 |  |  | Sudhakarrao Naik (MLA for Pusad Constituency No. 81-
 Yavatmal District)
 (Legislative Assembly)
 | 07 February 1983
 | 05 March 1985
 | 2 years, 26 days | Indian National Congress | Vasantdada III | .jpg) Vasantdada Patil
 | 
  | 19 |  |  | Balachandra Bhai Sawant (MLC for Elected by MLAs Constituency No. 09 -
 Ratnagiri District)
 (Legislative Council)
 | 12 March 1985
 | 03 June 1985
 | 83 days | Indian National Congress | Vasantdada IV | 
  | 20 |  |  | Ram Meghe (MLA for Daryapur Constituency No. 40-
 Amravati District)
 (Legislative Assembly)
 | 03 June 1985
 | 12 March 1986
 | 282 days | Indian National Congress | Nilangekar | Shivajirao Patil Nilangekar | 
  | 21 |  |  | Ram Meghe (MLA for Daryapur Constituency No. 40-
 Amravati District)
 (Legislative Assembly)
 | 12 March 1986
 | 26 June 1988
 | 2 years, 106 days | Indian National Congress | Shankarrao II | .jpg)  Shankarrao Chavan
 | 
  | 22 |  |  | Kamalkishor Kadam (MLA for Nanded Constituency No. 66-
 Nanded District
 (Legislative Assembly)
 | 26 June 1988
 | 03 March 1990
 | 1 year, 250 days | Indian National Congress | Pawar II |   Sharad Pawar
 | 
  | 23 |  |   | Vilasrao Deshmukh (MLA for Latur City Constituency No. 235-
 Latur District)
 (Legislative Assembly)
 | 03 March 1990
 | 25 June 1991
 | 1 year, 114 days | Indian National Congress | Pawar III | 
  | 24 |  |  | Anantrao Thopate (MLA for Bhor Constituency No. 203-
 Pune District
 (Legislative Assembly)
 | 25 June 1991
 | 22 February 1993
 | 1 year, 242 days | Indian National Congress | Sudhakarrao | Sudhakarrao Naik | 
  | 25 |  |  | Prabhakar Dharkar (MLC for Elected by MLAs Constituency No. 16 -
 Pune District)
 (Legislative Council)
 | 06 March 1993
 | 18 November 1994
 | 1 year, 257 days | Indian National Congress | Pawar IV |   Sharad Pawar
 | 
  | 26 |  |   | Prakash Mehta (MLA for Ghatkopar East Constituency No. 170-
 Mumbai Suburban District
 (Legislative Assembly)
 | 14 March 1995
 | 01 February 1999
 | 3 years, 324 days | Bharatiya Janata Party | Joshi |   Manohar Joshi
 | 
  | 27 |  |  | Sureshdada Jain (MLA for Jalgaon City Constituency No. 13-
 Jalgaon District
 (Legislative Assembly)
 | 01 February 1999
 | 11 May 1999
 | 99 days | Shiv Sena | Rane | .jpg)  Narayan Rane
 | 
  | 28 |  |   | Prakash Mehta (MLA for Ghatkopar East Constituency No. 170-
 Mumbai Suburban District
 (Legislative Assembly)
 | 11 May 1999
 | 17 October 1999
 | 159 days | Bharatiya Janata Party | 
  | 29 |  |   | Vilasrao Deshmukh (MLA for Latur City Constituency No. 235-
 Latur District)
 (Legislative Assembly)
 (Chief Minister)
 | 19 October 1999
 | 27 October 1999
 | 8 days | Indian National Congress | Deshmukh I |   Vilasrao Deshmukh
 | 
  | 30 |  |   | Dilip Walse-Patil (MLA for Ambegaon Constituency No. 196-
 Pune District)
 (Legislative Assembly)
 | 27 October 1999
 | 16 January 2003
 | 3 years, 81 days | Nationalist Congress Party | 
  | 31 |  |  | Ramkrishna More (MLA for Khed Constituency No. 219-
 Pune District)
 (Legislative Assembly)
 | 18 January 2003
 | 01 November 2004
 | 1 year, 295 days | Indian National Congress | Sushilkumar | .jpg)  Sushilkumar Shinde
 | 
  | 32 |  |   | R. R. Patil (MLA for Tasgaon-Kavathe Mahankal Constituency No. 287-
 Sangli District)
 (Legislative Assembly)
 (Deputy Chief Minister)
 | 01 November 2004
 | 09 November 2004
 | 8 days | Nationalist Congress Party | Deshmukh II |   Vilasrao Deshmukh
 | 
  | 33 |  |  | Sureshdada Jain (MLA for Jalgaon City Constituency No. 13-
 Jalgaon District
 (Legislative Assembly)
 | 09 November 2004
 | 01 December 2008
 | 4 years, 22 days | Nationalist Congress Party | 
  | 34 |  |  | Rajesh Tope (MLA for Ghansawangi Constituency No. 100-
 Jalna District
 (Legislative Assembly)
 | 08 December 2008
 | 06 November 2009
 | 333 days | Nationalist Congress Party | Ashok I |  Ashok Chavan
 | 
  | 35 |  |  | Rajesh Tope (MLA for Ghansawangi Constituency No. 100-
 Jalna District
 (Legislative Assembly)
 | 07 November 2009
 | 10 November 2010
 | 1 year, 3 days | Nationalist Congress Party | Ashok II | 
  | 36 |  |   | Prithviraj Chavan (MLC for Elected by MLAs Constituency No. 19 -
 Satara District)
 (Legislative Council)
 (Chief Minister)
 | 11 November 2010
 | 26 September 2014
 | 3 years, 319 days | Indian National Congress | Prithviraj |  Prithviraj Chavan
 | 
  | 37 |  |   | Vinod Tawde (MLA for Borivali Constituency No. 152-
 Mumbai Suburban District
 (Legislative Assembly)
 | 31 October 2014
 | 12 November 2019
 | 5 years, 12 days | Bharatiya Janata Party | Fadnavis I | .jpg)  Devendra Fadnavis
 | 
  | 38 |  |   | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52-
 Nagpur District)
 (Legislative Assembly)
 (Chief_Minister)
 In Charge
 | 23 November 2019
 | 28 November 2019
 | 5 days | Bharatiya Janata Party | Fadnavis II | 
  | 39 |  |   | Subhash Desai (MLC for Elected by MLAs Constituency No. 09 -
 Mumbai Suburban District)
 (Legislative Council)
 | 28 November 2019
 | 30 December 2019
 | 32 days | Shiv Sena | Thackeray | _(cropped).jpg)  Uddhav Thackeray
 | 
  | 40 |  |   | Uday Samant (MLA for Ratnagiri Constituency No. 266-
 Ratnagiri District
 (Legislative Assembly)
 | 30 December 2019
 | 27 June 2022
 | 2 years, 179 days | Shiv Sena | 
  | 41 |  | .jpg)  | Aaditya Thackeray (MLA for Worli Constituency No. 182-
 Mumbai City District
 (Legislative Assembly)
 | 27 June 2022
 | 29 June 2022
 | 2 days | Shiv Sena | 
  | 42 |  |   | Eknath Shinde (MLA for Kopri-Pachpakhadi Constituency No. 147-
 Thane District)
 (Legislative Assembly)
 (Chief Minister)
 In Charge
 | 30 June 2022
 | 14 August 2022
 | 45 days | Shiv Sena (Shinde Group) | Eknath |   Eknath Shinde
 | 
  | 43 |  |   | Chandrakant Patil (MLA for Kothrud Constituency No. 210-
 Pune District)
 (Legislative Assembly)
 | 14 August 2022
 | 26 November 2024
 | 2 years, 135 days | Bharatiya Janata Party | 
  | 44 |  |   | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52-
 Nagpur District)
 (Legislative Assembly)
 (Chief_Minister)
 In Charge
 | 05 December 2024
 | 21 December 2024
 | 16 days | Bharatiya Janata Party | Fadnavis III | .jpg)  Devendra Fadnavis
 | 
  | 45 |  |   | Chandrakant Patil (MLA for Kothrud Constituency No. 210-
 Pune District)
 (Legislative Assembly)
 | 21 December 2024
 | Incumbent | 243 days | Bharatiya Janata Party |