| No. | Portrait | Minister (Constituency) | Term of office | Political party | Ministry | Chief Minister |
| From | To | Period |
| Minister of Ex. Servicemen Welfare |
| 01 | | | Marotrao Kannamwar (MLA for Saoli Constituency No. 73- Chandrapur District) (Legislative Assembly) | 01 May 1960 | 07 March 1962 | 1 year, 310 days | Indian National Congress | Yashwantrao I | Yashwantrao Chavan |
| 02 | | | Shankarrao Chavan (MLA for Bhokar Constituency No. 85- Nanded District) (Legislative Assembly) | 08 March 1962 | 19 November 1962 | 256 days | Indian National Congress | Yashwantrao II |
| 03 | | | Parashuram Krishnaji Sawant (MLA for Chiplun Constituency No. 265- Ratnagiri District) (Legislative Assembly) | 20 November 1962 | 24 November 1963 | 1 year, 4 days | Indian National Congress | Kannamwar l | Marotrao Kannamwar |
| 04 | | | Parashuram Krishnaji Sawant (MLA for Chiplun Constituency No. 265- Ratnagiri District) (Legislative Assembly) (Interim Chief Minister) | 25 November 1962 | 04 December 1963 | 9 days | Indian National Congress | Sawant | Parashuram Krishnaji Sawant |
| 05 | | | Vasantrao Naik (MLA for Pusad Constituency No. 81- Yavatmal District) (Legislative Assembly) (Chief Minister) | 05 December 1963 | 01 March 1967 | 3 years, 86 days | Indian National Congress | Vasantrao I |  Vasantrao Naik |
| 06 | | | Vasantrao Naik (MLA for Pusad Constituency No. 81- Yavatmal District) (Legislative Assembly) (Chief Minister) | 01 March 1967 | 27 October 1969 | 2 years, 240 days | Indian National Congress | Vasantrao II |
| 07 | | | Shankarrao Chavan (MLA for Bhokar Constituency No. 85- Nanded District) (Legislative Assembly) | 27 October 1969 | 13 March 1972 | 2 years, 138 days | Indian National Congress |
| 08 | | | Yashwantrao Mohite (MLA for Karad South Constituency No. 260- Satara District) (Legislative Assembly) | 13 March 1972 | 04 April 1973 | 1 year, 32 days | Indian National Congress | Vasantrao III |
| 09 | | | Hari Govindrao Vartak (MLA for Bassein-Vasai Constituency No. 180- Palghar District (Legislative Assembly) | 04 April 1973 | 17 Match 1974 | 347 days | Indian National Congress |
| 10 | | | Vasantdada Patil (MLA for Sangli Constituency No. 282 - Sangli District) (Legislative Assembly) | 17 Match 1974 | 21 February 1975 | 341 days | Indian National Congress |
| 11 | | | Abdul Rahman Antulay (MLA for Shrivardhan Constituency No. 193- Raigad District) (Legislative Assembly) | 21 February 1975 | 16 April 1977 | 2 years, 54 days | Indian National Congress | Shankarrao I |  Shankarrao Chavan |
| 12 | | | Nashikrao Tirpude (MLA for Bhandara Constituency No. 61- Bhandara District) (Legislative Assembly) | 17 April 1977 | 07 March 1978 | 1 year, 324 days | Indian National Congress | Vasantdada I | .jpg) Vasantdada Patil |
| 13 | | | Baliram Waman Hiray (MLA for Dabhadi Constituency No. 74- Nashik District) (Legislative Assembly) | 07 March 1978 | 18 July 1978 | 133 days | Indian National Congress (Indira) | Vasantdada II |
| 14 | | | Jagannathrao Jadhav (MLA for Sangameshwar Constituency No. 173- Ratnagiri District (Legislative Assembly) | 18 July 1978 | 19 November 1979 | 1 year, 124 days | Janata Party | Pawar I | .jpg) Sharad Pawar |
| 15 | | | Surupsingh Hirya Naik (MLA for Navapur Constituency No. 04- Nandurbar District) (Legislative Assembly) | 09 June 1980 | 21 January 1982 | 1 year, 226 days | Indian National Congress | Antulay | Abdul Rahman Antulay |
| 16 | | | Babasaheb Bhosale (MLA for Nehrunagar Constituency No. 172- Mumbai Suburban District) (Legislative Assembly) (Chief Minister) | 21 January 1982 | 11 October 1982 | 263 days | Indian National Congress | Bhosale | Babasaheb Bhosale |
| 17 | | | Pratibha Patil (MLA for Jalgaon City Constituency No. 13- Jalgaon District) (Legislative Assembly) | 11 October 1982 | 02 February 1983 | 114 days | Indian National Congress |
| 18 | | | Ramrao Adik (MLC for Elected by MLAs Constituency No. 05 - Ahmednagar District) (Legislative Council) (Deputy Chief Minister) | 07 February 1983 | 05 March 1985 | 2 years, 26 days | Indian National Congress | Vasantdada III | .jpg) Vasantdada Patil |
| 19 | | | Vasantdada Patil (MLA for Sangli Constituency No. 282 - Sangli District) (Legislative Assembly) (Chief Minister) | 12 March 1985 | 03 June 1985 | 83 days | Indian National Congress | Vasantdada IV |
| 20 | | | Vijaysinh Mohite-Patil (MLA for Malshiras Constituency No. 254- Solapur District) (Legislative Assembly) | 03 June 1985 | 12 March 1986 | 282 days | Indian National Congress | Nilangekar | Shivajirao Patil Nilangekar |
| 21 | | | V. Subramanian (MLA for South Mumbai Constituency No. 121- Mumbai City District) (Legislative Assembly) | 12 March 1986 | 26 June 1988 | 2 years, 106 days | Indian National Congress | Shankarrao II | Shankarrao Chavan |
| 22 | | | Sushilkumar Shinde (MLA for Solapur City Central Constituency No. 249- Solapur District) (Legislative Assembly) | 26 June 1988 | 03 March 1990 | 1 year, 250 days | Indian National Congress | Pawar II | Sharad Pawar |
| 23 | | | Narendra Marutrao Kamble (MLC for Elected by Governor Nominated No. 10 - Mumbai City District) (Legislative Council) | 03 March 1990 | 25 January 1991 | 328 days | Indian National Congress | Pawar III |
| 24 | | | Jawaharlal Darda (MLC for Elected by MLAs Constituency No. 19 - Yavatmal District) (Legislative Council) | 25 January 1991 | 25 June 1991 | 151 days | Indian National Congress |
| 25 | | | Shivajirao Deshmukh (MLC for Elected by MLAs Constituency No. 18 - Sangli District) (Legislative Council) | 25 June 1991 | 22 February 1993 | 1 year, 242 days | Indian National Congress | Sudhakarrao | Sudhakarrao Naik |
| 26 | | | Ranjeet Deshmukh (MLA for Savner Constituency No. 49- Nagpur District) (Legislative Assembly) | 06 March 1993 | 18 November 1994 | 1 year, 257 days | Indian National Congress | Pawar IV | Sharad Pawar |
| 27 | | | Anna Dange (MLC for Elected by MLAs Constituency No. 05 - Sangli District) (Legislative Council) | 14 March 1995 | 01 February 1999 | 3 years, 324 days | Bharatiya Janata Party | Joshi | Manohar Joshi |
| 28 | | | Narayan Rane (MLA for Malvan Constituency No. 269- Sindhudurg District) (Legislative Assembly) (Chief Minister) | 01 February 1999 | 11 May 1999 | 99 days | Shiv Sena | Rane | Narayan Rane |
| 29 | | | Gopinath Munde (MLA for Renapur Constituency No. 236 - Latur District) (Legislative Assembly) (Deputy Chief Minister) | 11 May 1999 | 17 October 1999 | 159 days | Bharatiya Janata Party |
| 30 | | | Vilasrao Deshmukh (MLA for Latur City Constituency No. 235- Latur District) (Legislative Assembly) (Chief Minister) | 19 October 1999 | 27 October 1999 | 8 days | Indian National Congress | Deshmukh I | Vilasrao Deshmukh |
| 31 | | | Vilasrao Balkrishna Patil (MLA for Karad South Constituency No. 260- Satara District) (Legislative Assembly) | 27 October 1999 | 16 January 2003 | 3 years, 81 days | Indian National Congress |
| 32 | | | Ramkrishna More (MLA for Khed Constituency No. 219- Pune District) (Legislative Assembly) | 18 January 2003 | 01 November 2004 | 1 year, 295 days | Indian National Congress | Sushilkumar | Sushilkumar Shinde |
| 33 | | | Vilasrao Deshmukh (MLA for Latur City Constituency No. 235- Latur District) (Legislative Assembly) (Chief Minister) | 01 November 2004 | 09 November 2004 | 8 days | Indian National Congress | Deshmukh II | Vilasrao Deshmukh |
| 34 | | | Ashok Chavan (MLA for Bhokar Constituency No. 85- Nanded District) (Legislative Assembly) | 09 November 2004 | 01 December 2008 | 4 years, 22 days | Indian National Congress |
| 35 | | | Dilip Walse-Patil (MLA for Ambegaon Constituency No. 196- Pune District) (Legislative Assembly) | 08 December 2008 | 06 November 2009 | 333 days | Nationalist Congress Party | Ashok I |  Ashok Chavan |
| 36 | | | Mohammed Arif Naseem Khan (MLA for Chandivali Constituency No. 168- Mumbai Suburban District) (Legislative Assembly) | 07 November 2009 | 10 November 2010 | 1 year, 3 days | Indian National Congress | Ashok II |
| 37 | | | R. R. Patil (MLA for Tasgaon-Kavathe Mahankal Constituency No. 287- Sangli District) (Legislative Assembly) | 11 November 2010 | 26 September 2014 | 3 years, 319 days | Nationalist Congress Party | Prithviraj |  Prithviraj Chavan |
| 38 | | | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52- Nagpur District) (Legislative Assembly) (Chief Minister) | 31 October 2014 | 16 June 2019 | 4 years, 228 days | Bharatiya Janata Party | Fadnavis I | Devendra Fadnavis |
| 39 | | | Sambhaji Patil Nilangekar (MLA for Nilanga Constituency No. 238- Latur District (Legislative Assembly) | 16 June 2019 | 12 November 2019 | 149 days | Bharatiya Janata Party |
| 40 | | | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52- Nagpur District) (Legislative Assembly) (Chief_Minister) In Charge | 23 November 2019 | 28 November 2019 | 5 days | Bharatiya Janata Party | Fadnavis II |
| 41 | | | Eknath Shinde (MLA for Kopri-Pachpakhadi Constituency No. 147- Thane District) (Legislative Assembly) | 28 November 2019 | 30 December 2019 | 32 days | Shiv Sena | Thackeray | Uddhav Thackeray |
| 42 | | | Dadaji Bhuse (MLA for Malegaon Outer Constituency No. 81- Nashik District) (Legislative Assembly) | 30 December 2019 | 27 June 2022 | 2 years, 179 days | Shiv Sena |
| 43 | | | Shankarrao Gadakh (MLA for Nevasa Constituency No. 221- Ahmednagar District) (Legislative Assembly) Additional Charge | 27 June 2022 | 29 June 2022 | 2 days | Shiv Sena |
| 44 | | | Eknath Shinde (MLA for Kopri-Pachpakhadi Constituency No. 147- Thane District) (Legislative Assembly) (Chief Minister) In Charge | 30 June 2022 | 14 August 2022 | 45 days | Shiv Sena (Shinde Group) | Eknath | Eknath Shinde |
| 45 | | | Eknath Shinde (MLA for Kopri-Pachpakhadi Constituency No. 147- Thane District) (Legislative Assembly) (Chief Minister) | 14 August 2022 | 26 November 2024 | 2 years, 135 days | Shiv Sena (Shinde Group) |
| 46 | | | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52- Nagpur District) (Legislative Assembly) (Chief_Minister) In Charge | 05 December 2024 | 21 December 2024 | 16 days | Bharatiya Janata Party | Fadnavis III | Devendra Fadnavis |
| 47 | | | Shambhuraj Desai (MLA for Patan Constituency No. 261- Satara District) (Legislative Assembly) | 21 December 2024 | Incumbent | 239 days | Shiv Sena (Shinde Group) |